Triphenylacetic acid
- Product Name
- Triphenylacetic acid
- CAS No.
- 595-91-5
- Chemical Name
- Triphenylacetic acid
- Synonyms
- Triphenylacetate;TRITYLFORMIC ACID;TIMTEC-BB SBB008604;TRIPHENYLACETIC ACID;Acetic acid, triphenyl-;Triphenylaceticacid,99%;Lactic Acid Impurity 57;Triphenylacetic acid 99%;2,2,2-TRIPHENYLACETIC ACID;Triphenylacetic acid, HPLC 99%
- CBNumber
- CB8675374
- Molecular Formula
- C20H16O2
- Formula Weight
- 288.35
- MOL File
- 595-91-5.mol
Triphenylacetic acid Property
- Melting point:
- 270-273 °C (lit.)
- Boiling point:
- 390.57°C (rough estimate)
- Density
- 1.0992 (rough estimate)
- refractive index
- 1.7580 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- Fine Crystalline Powder
- pka
- pK1:3.96 (25°C)
- color
- White to beige
- InChI
- InChI=1S/C20H16O2/c21-19(22)20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H,(H,21,22)
- InChIKey
- DCYGAPKNVCQNOE-UHFFFAOYSA-N
- SMILES
- C(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C(=O)O
- CAS DataBase Reference
- 595-91-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Triphenylacetic acid(595-91-5)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- T81205
- Product name
- Triphenylacetic acid
- Purity
- 99%
- Packaging
- 5g
- Price
- $76.9
- Updated
- 2024/03/01
- Product number
- T81205
- Product name
- Triphenylacetic acid
- Purity
- 99%
- Packaging
- 10g
- Price
- $140
- Updated
- 2024/03/01
- Product number
- T1585
- Product name
- Triphenylacetic Acid
- Purity
- >97.0%(T)
- Packaging
- 5g
- Price
- $130
- Updated
- 2024/03/01
- Product number
- T1585
- Product name
- Triphenylacetic Acid
- Purity
- >97.0%(T)
- Packaging
- 25g
- Price
- $520
- Updated
- 2024/03/01
- Product number
- T895695
- Product name
- 2,2,2-TriphenylaceticAcid
- Packaging
- 5g
- Price
- $195
- Updated
- 2021/12/16
Triphenylacetic acid Chemical Properties,Usage,Production
Chemical Properties
white to beige fine crystalline powder
Uses
2,2,2-Triphenylacetic Acid is used in preparation of Rhodium(II) Tetramethyl-benzenedipropioate complex, other Carboxylate complexes, and their catalytic activity.
Application
Triphenylacetic acid could be used to seal dye molecules within MOF-5. Introducing triphenylacetic acid (TPAA) capping groups traps organic dyes such as crystal violet (CV) within the MOF crystals. Surface-bound TPAA groups block the MOF pores, preventing the encapsulated dye from diffusing into the solution. Liberating the TPAA from the surface by protonation can reverse guest trapping, but acidic conditions can also degrade the MOF by extruding the carboxylate struts. In addition, triphenylacetic acid could inhibit microsomal bilirubin UDPglucuronosyltransferase activity in rat liver. This compound competitively inhibits bilirubin UDP-glucuronosyltransferase with respect to bilirubin[2-3].
Synthesis Reference(s)
The Journal of Organic Chemistry, 28, p. 1725, 1963 DOI: 10.1021/jo01041a520
Reactivity Profile
Triphenylacetic acid can be selectively fluorinated in dimethylsulfoxide/ HgF2 solutions under UV-visible illumination[1].
References
[1] Habibi, Mohammed H., and T. E. Mallouk. "Photochemical selective fluorination of organic molecules using mercury (II) fluoride." Journal of Fluorine Chemistry 51.2(1991):291-294.
[2] Yan, J. , et al. "On-demand guest release from MOF-5 sealed with nitrophenylacetic acid photocapping groups. " Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 18.12(2019):2849-2853.
[3] Fournel, S, et al. "Inhibition of bilirubin UDPglucuronosyltransferase activity by triphenylacetic acid and related compounds. " BBA - General Subjects 883.2(1986):190-196.
Triphenylacetic acid Preparation Products And Raw materials
Raw materials
Preparation Products
Triphenylacetic acid Suppliers
- Tel
- (+1)-858-699-3322
- Fax
- (+1)-858-876-1948
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- Country
- United States
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- 8485655694
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- United States
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- United States
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- Tel
- +1-817863-6948 +1-（817）863-6948
- sales@aceschem.com
- Country
- United States
- ProdList
- 19639
- Advantage
- 58
View Lastest Price from Triphenylacetic acid manufacturers
- Product
- Triphenylacetic acid 595-91-5
- Price
- US $500.00-8000.00/kg
- Min. Order
- 0.1kg
- Purity
- 99%
- Supply Ability
- 2MT per month
- Release date
- 2023-11-21
- Product
- Triphenylacetic acid 595-91-5
- Price
- US $0.00/kg
- Min. Order
- 25kg
- Purity
- ≥98%
- Supply Ability
- Inquiry
- Release date
- 2022-10-28
- Product
- Triphenylacetic acid 595-91-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 0.99
- Supply Ability
- 1000kg
- Release date
- 2023-10-08